Diaquabis[5-(2-pyridyl)tetrazolato-κ2N1,N5]iron(II)

Diaquabis[5-(2-pyridyl)tetrazolato-κ2N1,N5]iron(II)

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The title complex, [Fe(C6H4N5)2(H2O)2], was synthesized by the reaction of ferrous sulfate with mini-dresses 5-(2-pyridyl)-2H-tetrazole (HL).The FeII atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water molecules in a distorted octahedral geometry.The FeII mononuclear units MEN KNIT LONG PANTS are further connected by intermolecular O—H.N and C—H.O hydrogen-bonding interactions, forming a three-dimensional framework.